Let $k$ be the number of red balls. Before looking at anything, all the values
$$
k=0,1,2,\dots,100
$$
They are equiprobable. But when observing that the first ball comes out red, the large values of $k$ become more plausible than the small ones, because an urn with many reds had more chances of producing that observation. The clean account is this. If there are $k$ reds, the probability of drawing red first and red later is
$$
\frac{k}{100}\cdot\frac{k-1}{99},
$$
while the probability of drawing red first is
$$
\frac{k}{100}.
$$ By averaging over all possible values of $k$ and conditioning on having seen red first, the result is reduced to comparing
$$
\sum_{k=0}^{100} k(k-1)
$$
with
$$
99\sum_{k=0}^{100} k.
$$ When you do the math you get exactly
$$
\frac23.
$$ Therefore, the probability that the second ball is also red is
$$
\frac23.
$$ $$